Abstract:
Thermal decomposition of complex salts [M(NH3)4]A (M = Pt, Pd; A = CrO4, Cr2O7) in oxygen atmosphere goes through the stage of formation of the phase MCrO2 with delafossite structure and it’s further decomposition and formation of the chromium oxide(III) and monometallic platinum or palladium. Thermal decomposition of complex salts [M(NH3)4]A (M = Pt, Pd; A = CrO4, Cr2O7) in hydrogen atmosphere proceeds with partial reduction of chromium to an metallic state and the formation of a metal solid solution MxCr1-x (M = Pt, Pd) with a chromium content up to 22 at.% and a chromium oxide(III). [..]
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