Abstract:
Two Prussian blue (PB) samples with different morphologies (spheres, mean size 160 nm; cubes, mean size 1.48 μm) and variable content of potassium (K-free and K-bearing) were used as a precursor material for the preparation of iron(III) oxides by solid state thermal decomposition method. A mixture of iron(III) oxide polymorphs (α-Fe2O3, β-Fe2O3, and γ-Fe2O3 nanoparticles) or pure maghemite (γ-Fe2O3 nanoparticles) were obtained by thermal decomposition of the cubic (K-bearing) or spherical (K-free) PB particles, respectively, at 350 °C in air. [..]
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