WET CHEMISTRY TREATMENT AND SURFACE MODIFICATION OF RECYCLED GLASS PARTICLES FOR SUSTAINABLE CONSTRUCTION APPLICATIONS

1 BABČENKO Oleg
Co-authors:
1 BERANOVÁ Klára 1 REMEŠ Zdeněk 1 KOLÁŘOVÁ Kateřina 1,2 LÖRINC Jakub 1,3 VOLF Jakub 2 PROŠEK Zdeněk 2 TESÁREK Pavel
Institutions:
1 Institute of Physics, Czech Academy of Sciences, Prague, Czech Republic, EU, babcenko@fzu.cz
2 Faculty of Civil Engineering, Czech Technical University in Prague, Prague, Czech Republic, EU
3 Department of Inorganic Chemistry, University of Chemistry and Technology, Prague, Czech Republic, EU
Conference:
16th International Conference on Nanomaterials - Research & Application, OREA Congress Hotel Brno, Czech Republic, EU, October 16 - 18, 2024
Proceedings:
Proceedings 16th International Conference on Nanomaterials - Research & Application
Pages:
151-157
ISBN:
978-80-88365-24-2
ISSN:
2694-930X
Published:
28th February 2025
Metrics:
32 views / 12 downloads
Abstract

The surface contamination or bulk impurities in the matrix of soda-lime glass can significantly alter glass properties and via leaching influenced the alternative glass waste utilization as a partial replacement for sand or binder in concrete-based materials for sustainable construction applications. Therefore, in this work, we perform wet chemistry (different pH) treatment of the recycled glass particles obtained from the commercial source. The resulting changes in glass particle properties were analyzed using microscopic and spectroscopic techniques. Changes in the concentrations of Mg, Al, Ca and Na near the particle surfaces were detected, indicating potential elements release. For instance, treatment in HCl resulted in a decrease of all observed non-silica ions in the glass subsurface region while NaOH treatment resulted in a slight increase of Ca amount in the subsurface region which potentially can positively affect the calcium-silicate-hydrate formation in concrete-based constructions. The observed results can be helpful in the explanation of processes at interfacial transition zones in waste glass containing concrete-based materials.

Keywords: Soda-lime glass, wet chemistry, surface analysis, metal ions diffusion, civil engineering

© This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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