EFFECT OF STEEL COMPOSITION ON ITS BEHAVIOUR IN THE LIQUID LEAD ENVIRONMENT

1 PAZDEROVÁ Martina
Co-authors:
1 HOJNÁ Anna 1 VÍT Jan 2 HADRABA Hynek 2 ČÍŽEK Jan
Institutions:
1 Centrum výzkumu Řež, Husinec-Řež, Czech Republic, EU, martina.pazderova@cvrez.cz
2 Institute of Physics of Materials, Czech Academy of Sciences, Brno, Czech Republic, EU
3 Institute of Plasma Physics of the Czech Academy of Sciences, Prague, Czech Republic, EU
Conference:
32nd International Conference on Metallurgy and Materials, Orea Congress Hotel Brno, Czech Republic, EU, May 17 - 19, 2023
Proceedings:
Proceedings 32nd International Conference on Metallurgy and Materials
Pages:
364-368
ISBN:
978-80-88365-12-9
ISSN:
2694-9296
Published:
8th January 2024
Proceedings of the conference were published in Web of Science.
Metrics:
290 views / 227 downloads
Abstract

Ferritic-martensitic Eurofer-97 and oxide dispersion strengthened (ODS) Eurofer steels are potential candidates for structural applications in advanced nuclear reactors. Influence of scandium, yttrium, and aluminum addition was studied at 600 °C using 10-6 wt.% oxygen concentration. Microstructure and corrosion behaviour was evaluated after 500 h and 1000 h of exposure to liquid lead. Microscopical investigation identified oxidation, solution-based attack, and Pb penetration into the material. Addition of scandium and aluminum changed the mechanism of corrosion attack. Eurofer-97 was partially protected by outer oxide and inner oxidation and Pb penetration was found. In contrast ODS-Eurofer steels after 1000 h of exposure showed mainly inner oxidation and SBA including Pb penetration into the steel. The inner oxidation consisted of Pb+Cr-O and Cr-O+Al-O layers mixture. Degradation of ODS steel was significantly lower than Eurofer-97. It seems that the inner oxidation layer beneath the surface did not prevent the Pb penetration but protected the surface from dissolution.

Keywords: Ferritic-martensitic steel, ODS, liquid Pb, oxidation, nuclear application

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