EFFECT OF CR AND NI ELEMENTS ON THE MICROSTRUCTURE AND PROPERTIES OF CU-FE-BASED IMMISCIBLE ALLOYS

1 LACOVÁ Anna
Co-authors:
1 ADAM Ondřej 1 JAN Vít
Institution:
1 Brno University of Technology, Faculty of Mechanical Engineering, Brno, Czech Republic, EU, Anna.Lacova@vutbr.cz, Ondrej.Adam@vutbr.cz, Jan@fme.vutbr.cz
Conference:
31st International Conference on Metallurgy and Materials, Orea Congress Hotel Brno, Czech Republic, EU, May 18 - 19, 2022
Proceedings:
Proceedings 31st International Conference on Metallurgy and Materials
Pages:
733-738
ISBN:
978-80-88365-06-8
ISSN:
2694-9296
Published:
1st November 2022
Proceedings of the conference were published in Web of Science and Scopus.
Metrics:
419 views / 195 downloads
Abstract

The immiscible Cu-Fe system is often used as a base for advanced heterogeneous alloys. With a suitable selection of alloying elements, it is possible to alloy individual phases and therefore tailor microstructure and final properties of a material as needed. To prepare the mentioned multicomponent alloys, it is necessary to understand the effect of individual alloying elements on the microstructure and properties of the Cu-Fe system. Although mostly used method in production of such materials is casting, mechanical alloying appears to be a suitable alternative, enabling a very fine microstructure to be created.The following study is focused on the characterization of Cu50Fe25Cr25 and Cu50Fe25Ni25 alloys and the effect of the alloying elements on their microstructure. Cr and Ni were selected as a BCC and FCC phase enhancing elements, respectively. The alloys were prepared by mechanical alloying using high-energy ball mill, with subsequent densification using spark plasma sintering. The microstructure of milled powders, as well as bulk samples, was examined, and the evolution of the microstructure during sintering evaluated with respect to the alloying elements. In addition, the hardness of bulk samples was measured. During the mechanical alloying a complete mixing was not achieved, as the milled powders were not single phase. However, a metastable FCC supersaturated solid solution was formed at least partially in both alloys, further decomposing into a multiphase microstructure after sintering

Keywords: Immiscible alloys, mechanical alloying, spark plasma sintering, heterogenous materials

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