CORROSION BEHAVIOUR OF AZ31 MAGNESIUM ALLOY IN SALINE CONTAINING GLUCOSE AT DIFFERENT CONCENTRATIONS

1 DOSKOČIL Leoš
Co-authors:
1 ŠOMANOVÁ Pavlína 1 WASSERBAUER Jaromír
Institution:
1 Brno University of Technology, Faculty of Chemistry, Brno, Czech Republic, EU, doskocil@fch.vut.cz
Conference:
31st International Conference on Metallurgy and Materials, Orea Congress Hotel Brno, Czech Republic, EU, May 18 - 19, 2022
Proceedings:
Proceedings 31st International Conference on Metallurgy and Materials
Pages:
549-554
ISBN:
978-80-88365-06-8
ISSN:
2694-9296
Published:
1st November 2022
Proceedings of the conference were published in Web of Science and Scopus.
Metrics:
349 views / 163 downloads
Abstract

AZ31 magnesium alloy was subjected to corrosion tests in a 0.9% NaCl containing 0 to 5 g/L D-glucose at 37°C. Potentiodynamic measurements were performed in corrosive environments with natural pH and with the pH set to 7.4. The results show that glucose in the range of 0.1 to 5 g/L led to a deterioration of the corrosion resistance of AZ31 alloy in 0.9% NaCl at an initial pH of 7.4. If the corrosive environment did not have a set pH, then a slightly different behavior was observed. Addition of 0.1 g/L glucose to 0.9% NaCl resulted in inhibition of corrosion, while higher concentrations accelerated corrosion. The corrosion aggravation was related to the oxidation of glucose to gluconic acid, which together with chlorides degraded the Mg(OH)2 layer on the AZ31 alloy surface. Surface analysis revealed that the corroded AZ31 alloy was covered with fine crystals in the absence of glucose.

Keywords: AZ31 magnesium alloy, corrosion, glucose, saline

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