INFLUENCE OF HUMIC ACID ON CORROSION OF LOW CARBON STEEL IN NEUTRAL AQUEOUS SOLUTION CONTAINING CHLORIDES

1 DOSKOČIL Leoš
Co-authors:
1 ŠOMANOVÁ Pavlína 1 BUCHTÍK Martin 1 HORÁK Tomáš 1 WASSERBAUER Jaromír
Institution:
1 Brno University of Technology, Faculty of Chemistry, Brno, Czech Republic, EU, doskocil@fch.vut.cz
Conference:
31st International Conference on Metallurgy and Materials, Orea Congress Hotel Brno, Czech Republic, EU, May 18 - 19, 2022
Proceedings:
Proceedings 31st International Conference on Metallurgy and Materials
Pages:
543-548
ISBN:
978-80-88365-06-8
ISSN:
2694-9296
Published:
1st November 2022
Proceedings of the conference were published in Web of Science and Scopus.
Metrics:
366 views / 158 downloads
Abstract

The effect of lignitic humic acid in 0.1 M NaCl at pH 7 on low carbon steel was investigated using potentiodynamic polarization and immersion test. The morphology and elemental composition of the corrosion products were characterized using scanning electron microscopy with energy dispersive spectroscopy. The results showed that humic acid accelerated the corrosion of low carbon steel in 0.1 M NaCl. The negative effect of humic acid was attributed to the complexation of the molecules with iron ions. After seven days, immersion tests revealed that steel in 0.1 M NaCl was covered with the discontinuous black corrosion products, whereas humic acid in 0,1 M NaCl induced the formation of a continuous layer of brown corrosion products with low adhesion to the surface. The elemental composition of the black and brown corrosion products corresponded to Fe3O4 and FeOOH, respectively.

Keywords: Humic acid, low carbon steel, corrosion, corrosion product

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