USE OF HYDROGEN-CONTAINING REM-BASED ADDITIONS IN DESIGNING RE-FE-B MAGNETIC MATERIALS

1 SKOTNICOVÁ Kateřina
Co-authors:
2 KOLCHUGINA Natalia B. 2 BURKHANOV Gennady S. 1 ČEGAN Tomáš 1 KURSA Miroslav 3 LUKIN Alexander A. 1 ŽIVOTSKÝ Ondřej 2,3 PROKOFEV Pavel A. 2 DORMIDONTOV Nikolay A. 1 JUŘICA Jan
Institutions:
1 VSB – Technical University of Ostrava, Faculty of Materials Science and Technology, 70800 Ostrava, Czech Republic, EU, katerina.skotnicova@vsb.cz
2 Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334 Moscow, Russia; nkolchugina@imet.ac.ru
3 Joint stock company «Spetsmagnit», 127238 Moscow, Russia; pav3387@yandex.ru
Conference:
29th International Conference on Metallurgy and Materials, Brno, Czech Republic, EU, May 20 - 22, 2020
Proceedings:
Proceedings 29th International Conference on Metallurgy and Materials
Pages:
964-970
ISBN:
978-80-87294-97-0
ISSN:
2694-9296
Published:
27th July 2020
Proceedings of the conference were published in Web of Science and Scopus.
Metrics:
640 views / 362 downloads
Abstract

The focusing of new technologies on the formation of inhomogeneous distributions of heavy rare-earth metals (REMs) in hard magnetic Nd-Fe-B materials is of scientific importance for increasing their functional properties, along with preserving existing sources of heavy REMs. The manufacturing process for these materials includes strip-casting, hydrogen decrepitation, and treatments in a hydrogen atmosphere, as well as high-energy milling combined with mechanical alloying of multicomponent powder mixtures. The role of alloying REMs and their alloys with transition metals on the formation of phase composition, microstructure, fine structure of grains, and the hysteretic properties of hard magnetic (RR')2Fe14B-based materials were investigated. These addition were introduced in the form of hydrides or hydrogenated alloys (TbHx, DyHx, ScHx, Tb3(Co,Cu), Dy3(Co,Cu)) to initial Nd(Pr)-Fe-B-based powder mixtures in the course of their mechanical activation. The new knowledge about the formation of the structured state of (RR')2Fe14B-phase grains, namely, the formation of compositional inhomogeneities of heavy REMs within grains was obtained. The core-shell grain structure so formed and the nonuniformity of the main hard magnetic phase lead to increases in the structure-sensitive magnetic parameters and to their higher stability during low-temperature annealing. The powder-blending manufacturing process allows us to prepare magnets with a wide range of hysteretic characteristics using unified initial Nd-Fe-B strip-casting alloys.

Keywords: Nd-Fe-B magnets, hydride, microstructure, REM distribution, magnetic properties.

© This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Scroll to Top