DEPOSITION OF ULTRA-BLACK NICKEL PHOSPHORUS COATINGS

1 SHCHERBINA Ekaterina
Co-authors:
1 ABRASHOV Aleksey 1 GRIGORYAN Nelya 1 ALESHINA Venera 1 VAGRAMYAN Tigran 1 MEN’SHIKOV Vladimir
Institution:
1 MUCTR - D. Mendeleev University of Chemical Technology of Russia, Moscow, Russia, katerina.sherbin@mail.ru
Conference:
29th International Conference on Metallurgy and Materials, Brno, Czech Republic, EU, May 20 - 22, 2020
Proceedings:
Proceedings 29th International Conference on Metallurgy and Materials
Pages:
782-787
ISBN:
978-80-87294-97-0
ISSN:
2694-9296
Published:
27th July 2020
Proceedings of the conference were published in Web of Science and Scopus.
Metrics:
685 views / 1142 downloads
Abstract

Absorbing surfaces of solar receivers are coated with black chrome, which provides the surface of steel or aluminum tubes with good absorption properties. However, the chrome coating does not protect well against corrosion because of its high porosity and high internal stresses, which cause a cracking of coatings. In this paper, we investigated two methods for formation of black coatings on chemically formed Ni-P layers: etching in nitric acid and anodic treatment in a phosphoric acid solution. It was found that in the course of processing the black coatings, their roughness and porosity increase. It was shown that nickel oxides NiO and Ni2O3 and nickel phosphates are presented in the coating composition. It was established that the heat treatment increases the wear resistance and protective ability of black coatings.

Keywords: Chemical nickel plating, ultra-black nickel-containing coatings, steel surface treatment, heat treatment of black coatings, Ni-P coatings, protective properties, roughness, XPS analysis of the composition

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