MICROSTRUCTURE AND MECHANICAL PROPERTIES OF NANOSTRUCTURED TI-22NB-10ZR COATINGS

1,2 FRUTOS Emilio
Co-authors:
3,4 KARLÍK Miroslav 5 JIMÉNEZ José Antonio 6 POLCAR Tomáš
Institutions:
1 Institute Pedro Nunes, Laboratory for Wear, Testing and Materials, Rua Pedro Nunes, 3030-199 Coimbra, Portugal, EU, etorres@ipn.pt
2 CEMMPRE-Center for Mechanical Engineering, Materials and Processes, University of Coimbra, Rua Luís Reis Santos, 3030-788, Coimbra, Portugal
3 Department of Materials, Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Trojanova 13, 120 00 Prague 2, Czech Republic, EU, Miroslav.Karlik@fjfi.cvut.cz
4 Department of Physics of Materials, Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 121 16 Prague 2, Czech Republic, EU
5 Centro Nacional de Investigaciones Metalúrgicas (CENIM-CSIC), Avd. Gregorio del Amo no 8, 28040 Madrid, Spain, EU, jimenez@cenim.csic.es
6 Department of Control Engineering, Faculty of Electrical Engineering, Czech Technical University in Prague, Technická 2, 160 00 Prague 6, Czech Republic, EU, polcar@fel.cvut.cz
Conference:
29th International Conference on Metallurgy and Materials, Brno, Czech Republic, EU, May 20 - 22, 2020
Proceedings:
Proceedings 29th International Conference on Metallurgy and Materials
Pages:
660-665
ISBN:
978-80-87294-97-0
ISSN:
2694-9296
Published:
27th July 2020
Proceedings of the conference were published in Web of Science and Scopus.
Metrics:
754 views / 465 downloads
Abstract

The design of implants and functional prostheses requires superficial modifications that promote fast and lasting osseointegration. Magnetron sputtering enables to design nanostructured and textured β-Ti rich Ti-22Nb-10Zr (wt.%) coatings with variable mechanical properties (hardness and Young’s modulus). Depending on the magnitude of the bias voltage used during deposition of the coating, martensitic transformation from the unstable β (bcc) to α” (orthorhombic) phase is activated. This transformation induces compressive residual stresses modifying the tensile strength, hardness and Young's modulus. The residual stresses were measured by nanoindentation, the microstructure and phase evolution were characterized by X-ray diffraction. The spatial phase distribution was determined by transmission electron microscopy. The calculated real hardness increases from 2.1 to 4.1 GPa as the bias voltage is increased from 0 to -148 V. The calculus confirms that the coating has a non-linear elastic behavior.

Keywords: Biomaterials, Non-toxic beta-rich Ti coatings, Martensitic phase transformation, Residual stresses, Nano-mechanical characterization

© This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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